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Organoboranes in Organic Syntheses

Organoboranes in Organic Syntheses

B5変 234ページ 上製
価格:3,080円 (消費税:280円)
ISBN978-4-8329-0362-3 C3043
奥付の初版発行年月:2010年11月 / 発売日:2010年11月中旬
発行:北海道大学出版会  
発売:北海道大学出版会
この大学出版部の本一覧
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内容紹介

2010年ノーベル化学賞受賞[鈴木カップリングの基本論文集]

著者プロフィール

Akira Suzuki(スズキ アキラ)

鈴木 章(すずき あきら)
北海道大学名誉教授
2010年度ノーベル化学賞

上記内容は本書刊行時のものです。

目次

●目次
Foreword  Herbert C. Brown

Acknowledgment

1 About the Author
  Research on Organoborane Chemistry / Sketch of Professor Akira Suzuki's Life / Awards / List of
 Publications (1967-2003)

2 Organoboranes as Sources of Organic Radicals
  Introduction / Reactions with α,β-Unsaturated Carbonyl Compounds / Oxygen-Induced Reaction
 of Trialkylboranes with Alkyl Halides. A Facile Coupling of Allylic and Benzylic Halides via  
 Triethylborane / A New Four-Carbon-Atom Homologation Involving the Free-Radical Chain Reaction
 of 1,3-Butadiene Monoxide with Organoboranes / Two Novel Reactions of Monomeric Formaldehyde
 with Trialkylboranes. A Remarkable Rapid Elimination Diverted by Oxygen to a Free-Radical Chain
 Addition / A Convenient Synthesis of α-Bromoketones from Vinyloxyboranes Obtained by the
 Reaction of Organoboranes with α,β-Unsaturated Ketones in the Presence of a Catalytic Amount
 of Oxygen / Oxygen-Induced 1,4-Addition Reaction of Organoboranes to Crotonaldimine / Reaction
 of Organoboranes with 1-Acyl-2-vinylcyclopropanes in the Presence of Oxygen / Reaction of
 Organoboranes with d-Carvone and l-Perillaldehyde in the Presence of Oxygen. Evidence for
 Coordination between Organoboranes and α,β-Unsaturated Carbonyl Oxygen in their
 Oxygen-Induced Free-Radical Reaction Process / Reaction of Organoboranes with Iron(III) Azide in
 the Presence of Hydrogen Peroxide. A Novel Synthesis of Azidoalkanes

3 Organic Syntheses Using Organoborates
  Introduction / Preparation of Tetracoordinate Organoborates / Synthesis via Organoborates
 (R3B-X-Y) with Latent Leaving Groups (Y) in the α-Position / Synthesis via Alkynylborates and
 Alkenylborates / Synthesis via Copper(I) Tetraorganoborates and Related Compounds /
 Miscellaneous Reactions / Summary

4 Haloboration of 1-Alkynes and Its Synthetic Application
  Introduction / Organic Synthesis via Haloboration Adducts Prepared from B-Halo-9-BBN / Organic
 Synthesis via Haloboration Adducts Prepared from Tribromoborane / Conclusion

5 Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds with Organic Electrophiles
  Introduction / Synthesis of Organoboron Reagents / Palladium-Catalyzed Reactions of
 Organoboron Compounds and Their Mechanism / Cross-Coupling Reaction / Head-to-Tail Coupling
 / Carbonylative Coupling / Alkoxycarbonylation and Dimerization / Conclusion


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